posted on 2019-05-29, 00:00authored byQikun Li, Sheng Bi, Jingyuan Bu, Chaolong Tang, Zhongliang Ouyang, Chengming Jiang, Jinhui Song
Characterizing
basic material properties, especially mechanical
properties, is the prerequisite for building reliable and durable
devices. As a promising semiconductor material, two-dimensional (2D)
organic–inorganic hybrid perovskites possess outstanding optical
and electrical properties and have attracted significant interest
for their wide energy applications. Therefore, a basic mechanical
property study of 2D perovskite material will both improve the understanding
of atomic layer-dependent property change and guide next-generation
novel device designs. Here, we report a direct shear modulus characterization
of 2D organic–inorganic hybrid (C4H9NH3)2PbBr4 perovskites in the ⟨001⟩
direction by atomic force microscopy. The measured shear modulus of
the 2D perovskite increases significantly with the decrease of the
atomic layers, especially as the layer number is less than 60. A composite
sandwich model to the free surface contractions of the molecular interaction
length is built to reveal this abnormal atomic layer-dependent mechanical
phenomenon. The characterization method and the sandwich model with
a rigid-elastic atomic interaction can be extended to analyze other
2D materials.