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An Unusual Approach to the Synthesis of Enantiomerically Cis Linear Homoallylic Alcohols Based on the Steric Interaction Mechanism of Camphor Scaffold

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journal contribution
posted on 15.04.2004, 00:00 by Chi-Lik Ken Lee, Cheng-Hsia Angeline Lee, Kui-Thong Tan, Teck-Peng Loh
Camphor is used as the chiral auxiliary for the enantioselective synthesis of cis linear homoallylic alcohols. A range of catalysts, aldehydes, and solvents were investigated to obtain the optimum yield, enantioselectivity, and cis olefinic geometry.

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