An Unprecedented Eight-Connected Self-Penetrating Coordination Framework Based on Cage-Shaped [Pb6(μ4-O)2(O2C)8] Clusters

Li, Dong-Sheng; Wu, Ya-Pan; Zhang, Peng; Du, Miao; Zhao, Jun; Li, Cheng-Peng; Wang, Yao-Yu

doi:10.1021/cg100090h.s002

cg100090h_si_002.pdf (3.2 MB)

An Unprecedented Eight-Connected Self-Penetrating Coordination Framework Based on Cage-Shaped [Pb₆(μ₄-O)₂(O₂C)₈] Clusters

journal contribution

posted on 2010-05-05, 00:00 authored by Dong-Sheng Li, Ya-Pan Wu, Peng Zhang, Miao Du, Jun Zhao, Cheng-Peng Li, Yao-Yu Wang

A unique self-penetrating coordination framework with (4²⁴.6⁴) network topology is constructed from cage-shaped [Pb₆(μ₄-O)₂(O₂C)₈] clusters as eight-connected nodes and long V-shaped dicarboxylate backbones as spacers, which interestingly can be regarded as the cross-linking of two interpenetrating six-connected pcu networks.