American Chemical Society
cg100090h_si_002.pdf (3.2 MB)

An Unprecedented Eight-Connected Self-Penetrating Coordination Framework Based on Cage-Shaped [Pb64-O)2(O2C)8] Clusters

Download (3.2 MB)
journal contribution
posted on 2010-05-05, 00:00 authored by Dong-Sheng Li, Ya-Pan Wu, Peng Zhang, Miao Du, Jun Zhao, Cheng-Peng Li, Yao-Yu Wang
A unique self-penetrating coordination framework with (424.64) network topology is constructed from cage-shaped [Pb64-O)2(O2C)8] clusters as eight-connected nodes and long V-shaped dicarboxylate backbones as spacers, which interestingly can be regarded as the cross-linking of two interpenetrating six-connected pcu networks.