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An “Umpolung Relay” Strategy: One-Pot, Twice Polarity Inversion Cascade Synthesis of Diversified [60]Fulleroindoles

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journal contribution
posted on 01.02.2021, 17:04 by Xin-Rui Chen, Ying-Meng Li, Xiang Li, Jun Xuan, Hong-Ping Zhou, Yu-Peng Tian, Fei Li
An “umpolung relay” strategy, which includes an one-pot, twice polarity inversion cascade of C60 via carbanion and carbocation polarity reversed relay pathway, has been developed for the synthesis of a diverse range of novel [60]­fulleroindole derivatives.