An Oxidized Active Site Model for the FeFe Hydrogenase: Reduction with Hydrogen Gas
journal contributionposted on 05.09.2011, 00:00 by Steven L. Matthews, D. Michael Heinekey
Models for the oxidized form of the FeFe hydrogenase active site have been prepared. These cationic complexes contain two iron atoms, carbonyl ligands, a propanedithiolate bridge, and one other bridging group. Reduction of these complexes with hydrogen gas is demonstrated.