An Intermolecular Hydroamination of Allenamides with Arylamines Catalyzed by Cationic Au(I) Salts

Hill, Anthony W.; R. J. Elsegood, Mark; Kimber, Marc C.

doi:10.1021/jo101035n.s001

An Intermolecular Hydroamination of Allenamides with Arylamines Catalyzed by Cationic Au(I) Salts

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posted on 2010-08-06, 00:00 authored by Anthony W. Hill, Mark R. J. Elsegood, Marc C. Kimber

An intermolecular hydroamination of allenamides with arylamines has been achieved under mild Au(I) catalysis conditions delivering allylamino E-enamides stereoselectively and in high yield. The reaction is made possible via a convenient method for conjugated N-acyliminium formation.

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allylamino Allenamide Cationic stereoselectively allenamide hydroamination SaltsAn Arylamines Catalyzed catalysi formation arylamine method Intermolecular Hydroamination

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An Intermolecular Hydroamination of Allenamides with Arylamines Catalyzed by Cationic Au(I) Salts

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