An Efficient Total Synthesis of (±)-Stemonamine

Zhao, Yu-Ming; Gu, Peiming; Tu, Yong-Qiang; Fan, Chun-An; Zhang, Qingwei

doi:10.1021/ol800433r.s001

An Efficient Total Synthesis of (±)-Stemonamine

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posted on 2008-05-01, 00:00 authored by Yu-Ming Zhao, Peiming Gu, Yong-Qiang Tu, Chun-An Fan, Qingwei Zhang

An efficient first approach to the Stemona alkaloid (±)-Stemonamine has been developed on the basis of a key TiCl₄ promoted tandem Semipinacol rearrangement/Schmidt reaction and a Dieckmann condensation reaction.

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alkaloid Efficient Stemonamine basis Dieckmann condensation reaction approach Synthesi Semipinacol Stemona tandem TiCl 4 rearrangement

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CC BY-NC 4.0

An Efficient Total Synthesis of (±)-Stemonamine

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