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An Efficient Catalyst System for Pd-Catalyzed Amination of [2.2]Paracyclophanyl Bromides

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journal contribution
posted on 04.09.2009, 00:00 by Bo Qu, Yudao Ma, Qingshuang Ma, Xiao Liu, Fuyan He, Chun Song
A practical Buchwald−Hartwig amination of [2.2]paracyclophanyl bromides with benzhydrylideneamine is developed. The method provides a facile route to a variety of imino and amino [2.2]paracyclophanes that are otherwise not readily synthesized.