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Amino-Aryl-Carbenes: Alternative Ligands for Transition Metals?

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journal contribution
posted on 11.02.2004, 00:00 authored by Xavier Cattoën, Heinz Gornitzka, Didier Bourissou, Guy Bertrand
Despite the presence of a single amino substituent, an amino-anthryl-carbene was found to behave as a strong σ-donor weak π-acceptor ligand toward rhodium(I) fragments.