om970075k_si_001.pdf (264.43 kB)
Download file

Aluminum Chloride Catalyzed Intramolecular Cyclization and Allylsilylation of Diallylsilanes

Download (264.43 kB)
journal contribution
posted on 05.08.1997, 00:00 by Bong Kwan Cho, Geun Mook Choi, Jung-Il Jin, Bok Ryul Yoo, Il Nam Jung
Reactions of diallylsilanes with allyltrimethylsilane in the presence of aluminum chloride as a catalyst resulted in intramolecularly cyclized allylsilylation products of trans- and cis-3-allyl-1,1-dimethyl-5-((trialkylsilyl)methyl)-1-silacyclohexanes in good yields. The reaction proceeded faster and gave better yields with the incorporation of chlorotrimethylsilane in the aluminum chloride catalyst.