Alkynyliodonium Salts in Organic Synthesis. Application to the
Preparation of the Tricyclic Core of (±)-Halichlorine

Feldman, Ken S.; Perkins, Angela L.; Masters, Katherine M.

doi:10.1021/jo0487911.s001

Alkynyliodonium Salts in Organic Synthesis. Application to the Preparation of the Tricyclic Core of (±)-Halichlorine

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posted on 2004-11-12, 00:00 authored by Ken S. Feldman, Angela L. Perkins, Katherine M. Masters

The tricyclic core of halichlorine has been synthesized through the use of an alkynyliodonium salt/alkylidenecarbene/1,5 C−H insertion sequence that sets the pivotal quaternary center in the target.

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sequence set insertion quaternary center application Organic Synthesis Halichlorine Alkynyliodonium Salts tricyclic core alkynyliodonium halichlorine Preparation Tricyclic Core

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