Alkali Metal Fluorides
in Fluorinated Alcohols: Fundamental
Properties and Applications to Electrochemical Fluorination

Shida, Naoki; Takenaka, Hiroaki; Gotou, Akihiro; Isogai, Tomohiro; Yamauchi, Akiyoshi; Kishikawa, Yosuke; Nagata, Yuuya; Tomita, Ikuyoshi; Fuchigami, Toshio; Inagi, Shinsuke

doi:10.1021/acs.joc.1c00692.s001

jo1c00692_si_001.pdf (3.28 MB)

Alkali Metal Fluorides in Fluorinated Alcohols: Fundamental Properties and Applications to Electrochemical Fluorination

journal contribution

posted on 2021-07-01, 16:34 authored by Naoki Shida, Hiroaki Takenaka, Akihiro Gotou, Tomohiro Isogai, Akiyoshi Yamauchi, Yosuke Kishikawa, Yuuya Nagata, Ikuyoshi Tomita, Toshio Fuchigami, Shinsuke Inagi

Fundamental properties of alkali metal fluorides (MF, M = Cs, K) dissolved in 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) or in 3,3,3-trifluoroethanol (TFE) are investigated, including solubility, conductivity, and viscosity. Solid-state structures of single crystals obtained from CsF/HFIP and CsF/TFE are described for the first time, giving insights into the multiple interactions between fluorinated alcohols and CsF. Applications in electrochemical fluorination reactions are successfully demonstrated.

Alkali Metal Fluorides in Fluorinated Alcohols: Fundamental Properties and Applications to Electrochemical Fluorination

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