jo5b00641_si_001.pdf (2.29 MB)
Air Oxidative Radical Oxysulfurization of Alkynes Leading to α‑Thioaldehydes
journal contributionposted on 2015-05-15, 00:00 authored by Shao-Fang Zhou, Xiang-Qiang Pan, Zhi-Hao Zhou, Adedamola Shoberu, Pei-Zhi Zhang, Jian-Ping Zou
Air oxidative radical oxysulfurization of alkynes initiated by 0.5 mol % tert-butyl hydroperoxide with arylthiols is described. The reaction proceeded at room temperature in the presence of 5% mol water to afford selective α-thioaldehydes.