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Addition of Carbamoylsilanes to Electrophilically Substituted Alkenes. Preparation of β-Functionalized Tertiary Amides

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journal contribution
posted on 03.03.2005, 00:00 by Robert F. Cunico, Adalie Rodriguez Motta
The Si−C bond of N,N-dimethylcarbamoylsilanes added regiospecifically to the CC bond of electrophilically functionalized alkenes to afford β-silyl-β-functionalized amides. Carbonyl addition products were formed when hindered alkenic esters were used.