ol1c03098_si_001.pdf (5.16 MB)
Activation of Chromium Catalysts by Photoexcited Hantzsch Ester for Decarboxylative Allylation of Aldehydes with Butadiene
journal contributionposted on 2021-10-04, 19:39 authored by Shuangjie Lin, Yuqing Chen, Huaipu Yan, Yonghong Liu, Yuchen Sun, Erjun Hao, Caizhe Shi, Dandan Zhang, Nan Zhu, Lei Shi
Metallaphotocatalysis often needs light-absorbing metal-polypyridyl complexes, semiconductors, or organic dyes, which can modify the oxidation state of metal catalysts. Here, we first report that photoexcitation of Hantzsch ester can directly activate chromium reagents through a single-electron transfer process. The synthetic application was demonstrated through a photoredox decarboxylative allylation of aldehydes with feedstock butadiene without exogenous photocatalysts, metallic reductants, or additives.