A Total Synthesis of
(±)-trans-Kumausyne

Chandler, Carley L.; Phillips, Andrew J.

doi:10.1021/ol051199t.s001

ol051199t_si_001.pdf (862.58 kB)

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A Total Synthesis of (±)-trans-Kumausyne

journal contribution

posted on 2005-08-04, 00:00 authored by Carley L. Chandler, Andrew J. Phillips

A short total synthesis of (±)-trans-kumausyne is reported. Key steps include a tandem ring-opening−ring-closing metathesis and the effective introduction of the pentenyl side chain by allylation−cross metathesis.

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A Total Synthesis of (±)-trans-Kumausyne

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Keywords

Total Synthesis kumausyne introduction Key steps synthesis metathesi tandem allylation pentenyl side chain tran Kumausyne

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