A Three-Dimensional Porous Metal−Organic Framework Constructed from Two-Dimensional Sheets via Interdigitation Exhibiting Dynamic Features

Ma, Shengqian; Sun, Daofeng; Forster, Paul M.; Yuan, Daqiang; Zhuang, Wenjuan; Chen, Yu-Sheng; Parise, John B.; Zhou, Hong-Cai

doi:10.1021/ic900372t.s001

ic900372t_si_001.pdf (358.81 kB)

A Three-Dimensional Porous Metal−Organic Framework Constructed from Two-Dimensional Sheets via Interdigitation Exhibiting Dynamic Features

journal contribution

posted on 2009-06-01, 00:00 authored by Shengqian Ma, Daofeng Sun, Paul M. Forster, Daqiang Yuan, Wenjuan Zhuang, Yu-Sheng Chen, John B. Parise, Hong-Cai Zhou

A three-dimensional porous metal−organic framework (PCN-18) was constructed through interdigitating two-dimensional grid sheets composed of 4,4′-(anthracene-9,10-diyl)dibenzoate and copper paddlewheel secondary building units, and its dynamic features were evidenced by gas sorption isotherms.