American Chemical Society
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A Secondary Reagent-Assisted Synthesis of A Novel NiII−MoIV Chiral Coordination Polymer

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journal contribution
posted on 2009-05-06, 00:00 authored by Wen Zhang, Zhi-Qiang Wang, Osamu Sato, Ren-Gen Xiong
With the aid of a secondary reagent [CuII(tren)](ClO4)2, a novel chiral one-dimensional coordination polymer, [NiII(tren)]3[MoIV(CN)8](ClO4)2·5H2O (1) (tren = tris(2-aminoethyl)amine), was inadvertently but reproducibly synthesized, which crystallizes in a chiral space group P212121 and shows a complex triple-stranded helical structure.