posted on 2016-10-28, 16:36authored byYong Cui, Bowei Xu, Bei Yang, Huifeng Yao, Sunsun Li, Jianhui Hou
Three
pH neutral conjugated polymers based on thiophene and benzene
derivatives, namely PCP-Na, PCF-Na, and PFS-Na, were designed and
synthesized. In the three polymers, PCP-Na exhibited a self-doping
effect in aqueous solution, and the thin film of PCP-Na demonstrated
a high electrical conductivity of 1.66 × 10–3 S/cm and a deep HOMO level of −5.22 eV; these properties
make it an ideal anode interfacial layer (AIL) material in polymer
solar cells (PSCs). The single-junction PSC modified with PCP-Na AIL
showed a PCE of 9.89%, which is comparable to that of the PEDOT:PSS-modified
device (PCE = 9.53%). Notably, PCP-Na AIL exhibited excellent thickness
insensitivity in fabricating PSC devices; i.e., the PSC devices with
very thick PCP-Na interlayers over 300 nm still demonstrated a high
fill factor over 70%, indicating the PCP-Na layer has excellent charge
collection and transport properties. Furthermore, the homo-tandem
PSC device was fabricated using a new connecting interlayer, which
consists of PCP-Na as the hole collection layer and ZnO as the electron
collection layer, and a PCE of 10.54% was achieved in the homo-tandem
device.