A Novel Approach to the CDE Ring System of Pectenotoxin-4 Triggered by VO(acac)2-Induced Epoxy-Acetalization

Carley, Sarah; Brimble, Margaret A.

doi:10.1021/ol8025457.s002

ol8025457_si_002.pdf (2.17 MB)

A Novel Approach to the CDE Ring System of Pectenotoxin-4 Triggered by VO(acac)₂-Induced Epoxy-Acetalization

journal contribution

posted on 2009-02-05, 00:00 authored by Sarah Carley, Margaret A. Brimble

A novel approach to the CDE fragment of pectenotoxin-4 is described wherein the bicyclic acetal is constructed via a cascade cyclization induced by VO(acac)₂ epoxidation of a homoallylic alcohol.

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Keywords

bicyclic acetal novel approach cascade cyclization Triggered CDE fragment Pectenotoxin VO pectenotoxin homoallylic alcohol Novel Approach epoxidation CDE Ring System

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