A New Route to a 2‑Phosphanaphthalene

Mao, Yanli; Meng Hui Lim, Kelvin; Ganguly, Rakesh; Mathey, Francois

doi:10.1021/ol302278p.s002

ol302278p_si_002.pdf (465.25 kB)

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A New Route to a 2‑Phosphanaphthalene

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posted on 2012-09-21, 00:00 authored by Yanli Mao, Kelvin Meng Hui Lim, Rakesh Ganguly, Francois Mathey

The reaction between methylenechlorophosphine-pentacarbonyltungsten and an isobenzofuran affords a [4 + 2] adduct whose oxygen bridge is broken by BBr₃, leading to a 2-phosphanaphthalene.

A New Route to a 2‑Phosphanaphthalene

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