A New, Convenient Synthesis of the Linear Phosphazene Salt
[Cl3PNPCl3]Cl:  Preparation of Higher Linear Homologues
[Cl3PN−(PCl2N)xPCl3]Cl (x = 1−3) and the 16-Membered
Macrocycle [NCCl(NPCl2)3]2

Rivard, Eric; Lough, Alan J.; Manners, Ian

doi:10.1021/ic049955z.s002

A New, Convenient Synthesis of the Linear Phosphazene Salt [Cl₃PNPCl₃]Cl: Preparation of Higher Linear Homologues [Cl₃PN−(PCl₂N)_xPCl₃]Cl (x = 1−3) and the 16-Membered Macrocycle [NCCl(NPCl₂)₃]₂

journal contribution

posted on 2004-05-03, 00:00 authored by Eric Rivard, Alan J. Lough, Ian Manners

An improved synthetic route to the linear phosphazene salt [Cl₃PNPCl₃]Cl is reported. This species is a useful precursor to higher linear homologues and also to heterocycles such as the 16-membered carbophosphazene macrocycle [NCCl(NPCl₂)₃]₂.