American Chemical Society
om5b00761_si_001.pdf (727.17 kB)

A Luminescent 3D Organometallic Network Based on Silver Clusters and Star-like Tris(4-ethynylphenyl)amine

Download (727.17 kB)
journal contribution
posted on 2015-10-26, 00:00 authored by Bao Li, Tianle Zhang
A star-like tris­(4-ethynylphenyl)­amine was used as a ligand to link Ag30 and Ag17 cluster units via argentophilic, Ag­(I)-ethynide, and Ag-nitrate interactions to construct one 3D organometallic network possessing small cavities. The solid network displays a yellowish-green emission at room temperature.