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A General Protocol for Addressing Speciation of the Active Catalyst Applied to Ligand-Accelerated Enantioselective C(sp3)–H Bond Arylation

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journal contribution
posted on 18.01.2018, 00:00 by David E. Hill, Qing-lan Pei, En-xuan Zhang, James R. Gage, Jin-Quan Yu, Donna G. Blackmond
The potential role of dimeric catalyst species on or off the catalytic cycle is considered for a case of Pd-catalyzed C–H functionalization, leading to the development of a general experimental protocol that uses the reaction itself to report on the presence and role of dimeric species in asymmetric catalytic reactions.