cs8b00103_si_001.pdf (1.13 MB)
A General Protocol for Addressing Speciation of the Active Catalyst Applied to Ligand-Accelerated Enantioselective C(sp3)–H Bond Arylation
journal contribution
posted on 2018-01-18, 00:00 authored by David
E. Hill, Qing-lan Pei, En-xuan Zhang, James R. Gage, Jin-Quan Yu, Donna G. BlackmondThe potential role
of dimeric catalyst species on or off the catalytic
cycle is considered for a case of Pd-catalyzed C–H functionalization,
leading to the development of a general experimental protocol that
uses the reaction itself to report on the presence and role of dimeric
species in asymmetric catalytic reactions.