om900067f_si_001.pdf (205.16 kB)
Download file

A 14-VE Platinum(0) Phosphabarrelene Complex in the Hydrosilylation of Alkynes

Download (205.16 kB)
journal contribution
posted on 27.04.2009, 00:00 by Matthias Blug, Xavier-Frederic Le Goff, Nicolas Mézailles, Pascal Le Floch
A bulky phosphabarrelene ligand is used in the platinum-catalyzed hydrosilylation of alkynes. High regioselectivities were achieved under mild conditions from an in situ formed catalyst at low catalyst loadings. Furthermore, a rare 14-VE PtL2 complex was isolated, which equally proved to be a highly reactive catalyst precursor.