3D Printing of Cellulose Nanocrystal-Loaded Hydrogels through Rapid Fixation by Photopolymerization
journal contributionposted on 2021-05-19, 04:44 authored by Doron Kam, Ariel Braner, Avi Abouzglo, Liraz Larush, Annalisa Chiappone, Oded Shoseyov, Shlomo Magdassi
New ink compositions for direct ink writing (DIW) printing of hydrogels, combining superior rheological properties of cellulose nanocrystals (CNCs) and a water-compatible photoinitiator, are presented. Rapid fixation was achieved by photopolymerization induced immediately after the printing of each layer by 365 nm light for 5 s, which overcame the common height limitation in DIW printing of hydrogels, and enabled the fabrication of objects with a high aspect ratio. CNCs imparted a unique rheological behavior, which was expressed by orders of magnitude difference in viscosity between low and high shear rates and in rapid high shear recovery, without compromising ink printability. Compared to the literature, the presented printing compositions enable the use of low photoinitiator concentrations at a very short build time, 6.25 s/mm, and are also curable by 405 nm light, which is favorable for maintaining viability in bioinks.
Read the peer-reviewed publication
shear rates365 nm lightwater-compatible photoinitiatorCellulose Nanocrystal-Loaded Hydrogelshydrogelrheological behaviorRapid fixation3 D Printingaspect ratiorheological propertiesphotoinitiator concentrationsshear recoveryPhotopolymerization New ink composi...height limitationDIW printingCNC405 nm lightink printabilitycellulose nanocrystalsprinting compositionsRapid Fixationmagnitude difference