Versatile Synthesis of Phospholides from Open-Chain Precursors. Application to Annelated Pyrrole– and Silole–Phosphole Rings
journal contributionposted on 03.04.2015 by Youzhi Xu, Zhihua Wang, Zhenjie Gan, Qiuzhen Xi, Zheng Duan, François Mathey
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Phospholides are easily obtained by treatment of the open-chain acetylenic phosphines shown by an excess of lithium at room temperature in THF (12 examples).