ic701320d_si_004.pdf (1.45 MB)

Unprecedented Examples of Heterobimetallic Cerium(IV) Disiloxanediolates

Download (1.45 MB)
journal contribution
posted on 01.10.2007 by Stephan Giessmann, Steffen Blaurock, Volker Lorenz, Frank T. Edelmann
The first disiloxanediolate complexes of cerium(IV) are reported. Starting from the readily available precursor (tBuO)3CeIV(NO3)(THF)2 (1), we prepared the novel heterobimetallic compounds [{(Ph2SiO)2O}{K(THF)2}]2Ce(OtBu)2 (2) and [{(Ph2SiO)2O}2{(DME)-KOtBu}{(Ph2SiO2)K}Ce]2 (3) and structurally characterized them by X-ray diffraction.

History

Exports