jo3028246_si_001.pdf (2.28 MB)
0/0

Understanding the Reactivity of Enol Ether Radical Cations: Investigation of Anodic Four-Membered Carbon Ring Formation

Download (2.28 MB)
journal contribution
posted on 19.02.2016 by Yusuke Yamaguchi, Yohei Okada, Kazuhiro Chiba
The reactivity of enol ether radical cations was investigated in anodic four-membered carbon ring formations, advancing the mechanistic understanding of these reactions. The mono-ring-containing aromatic cations were reduced through inter- or intramolecular electron transfer to give mono- or bis-ring-containing compounds, respectively. Small structural changes in the hydrocarbon linkers tethering two aromatic rings exerted a powerful effect on the efficiency of such electron transfer events.

History

Exports