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Total Synthesis of Epicoccin G

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journal contribution
posted on 01.06.2011, 00:00 by K. C. Nicolaou, Sotirios Totokotsopoulos, Denis Giguère, Ya-Ping Sun, David Sarlah
An expedient enantioselective total synthesis of epicoccin G and related dithiodiketopiperazines through a strategy featuring direct two-directional sulfenylation, photooxygenation, and Kornblum–DeLaMare rearrangement is described.