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The First General Method for Z-Selective Olefination of Acylsilanes via Ynolate Anions Providing Multisubstituted Alkenes

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journal contribution
posted on 22.05.2002, 00:00 by Mitsuru Shindo, Kenji Matsumoto, Seiji Mori, Kozo Shishido
We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-β-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.