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Suzuki Coupling Reaction of 1,6,7,12-Tetrabromoperylene Bisimide

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journal contribution
posted on 02.03.2006 by Wenfeng Qiu, Shiyan Chen, Xiaobo Sun, Yunqi Liu, Daoben Zhu
1,6,7,12-Tetrabromoperylene-3,4,9,10-tetracarboxylic acid bisanhydride and the corresponding tetrabrominated perylene bisimide were first synthesized with high yields. The Suzuki coupling reaction of novel tetrabromoperylene bisimide with phenylbonoric acid was studied. The four bromines in the bay position of the perylene core were substituted successfully to yield 1,6,7,12-teraphenylperylene bisimide. The photochemical properties of the novel perylene bisimides were studied and presented.