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Rhodium(III)-Catalyzed Azacycle-Directed Intermolecular Insertion of Arene C–H Bonds into α‑Diazocarbonyl Compounds

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journal contribution
posted on 07.06.2013 by Xinzhang Yu, Songjie Yu, Jian Xiao, Boshun Wan, Xingwei Li
Cp*Rh­(III)-catalyzed intermolecular C–C couplings between activated α-diazocarbonyl compounds and arenes bearing a range of azacyclic directing groups have been achieved. This catalytic alkylation reaction operates under mild conditions with good functional group tolerance.