Rhodium(III)-Catalyzed Azacycle-Directed Intermolecular Insertion of Arene C–H Bonds into α‑Diazocarbonyl Compounds
journal contributionposted on 07.06.2013 by Xinzhang Yu, Songjie Yu, Jian Xiao, Boshun Wan, Xingwei Li
Any type of content formally published in an academic journal, usually following a peer-review process.
Cp*Rh(III)-catalyzed intermolecular C–C couplings between activated α-diazocarbonyl compounds and arenes bearing a range of azacyclic directing groups have been achieved. This catalytic alkylation reaction operates under mild conditions with good functional group tolerance.