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Rhodium(III)-Catalyzed Selective C–H Acetoxylation and Hydroxylation Reactions

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journal contribution
posted on 19.06.2017 by Yunxiang Wu, Bing Zhou
An efficient Cp*Rh­(III)-catalyzed, chelation-assisted C­(sp2)–H acetoxylation and hydroxylation reaction has been developed for the first time. The reaction proceeds under mild conditions and allows for selective preparation of C–H acetoxylation and hydroxylation products, thus providing a good complement to previous C–H oxygenation reactions and expanding the field of Cp*Rh­(III)-catalyzed C–H functionalizations.