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Regio- and Stereocontrolled Nucleophilic Addition Reactions of a Phenylthio-Substituted Cyclohexadiene-Containing η4-Molybdenum Cationic Complex

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journal contribution
posted on 01.10.1996 by Shang-Shing P. Chou, Hui-Tuo Sheng
The reaction of a new cationic complex, [Cp(CO)2Mo(η4-2-SPh-C6H7)]+PF6- (3), with carbon and sulfur nucleophiles was found to give in most cases the C-4 addition products 4 in good yield. The X-ray crystal structure of one of the addition products 4b confirms the regio- and stereochemistry of the reaction.