Re(I)-Catalyzed Hydropropargylation of Silyl Enol Ethers Utilizing Dynamic Interconversion of Vinylidene–Alkenylmetal Intermediates via 1,5-Hydride Transfer
journal contributionposted on 12.06.2018 by Nobuharu Iwasawa, Shoya Watanabe, Akane Ario, Hideyuki Sogo
Any type of content formally published in an academic journal, usually following a peer-review process.
Re(I)-catalyzed hydropropargylation reaction of silyl enol ethers was realized utilizing dynamic interconversion of vinylidene–alkenylmetal intermediates, where alkenylmetals underwent 1,5-hydride transfer of the α-hydrogen to generate vinylidene intermediates. Furthermore, this process was found to be in an equilibrium.