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Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes

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journal contribution
posted on 02.10.2017 by Pei-Zhi Zhang, Ling Zhang, Jian-An Li, Adedamola Shoberu, Jian-Ping Zou, Wei Zhang
A double-functionalization reaction of alkenes through Mn­(OAc)3-mediated phosphinoyl radical addition followed by CuCN-catalyzed cyanation is introduced. This one-pot reaction is performed under mild conditions to afford vicinal cyanophosphinoylation products.