Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes
journal contributionposted on 02.10.2017 by Pei-Zhi Zhang, Ling Zhang, Jian-An Li, Adedamola Shoberu, Jian-Ping Zou, Wei Zhang
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A double-functionalization reaction of alkenes through Mn(OAc)3-mediated phosphinoyl radical addition followed by CuCN-catalyzed cyanation is introduced. This one-pot reaction is performed under mild conditions to afford vicinal cyanophosphinoylation products.