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Palladium-Catalyzed Selective Acyloxylation Using Sodium Perborate as Oxidant

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journal contribution
posted on 04.03.2011 by Lukasz T. Pilarski, Pär G. Janson, Kálmán J. Szabó
Sodium perborate (SPB), a principal component of washing powders, was employed as an inexpensive and eco-friendly oxidant in the palladium-catalyzed C−H acyloxylation of alkenes in excellent regio- and stereochemistry. The reactions used anhydrides as acyloxy sources. The method applies to both terminal and internal alkenes, and even benzylic C−H oxidation.

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