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Palladium-Catalyzed Enantioselective Oxidation of Alcohols:  A Dramatic Rate Acceleration by Cs2CO3/t-BuOH

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journal contribution
posted on 14.02.2003 by Jeffrey T. Bagdanoff, Eric M. Ferreira, Brian M. Stoltz
The addition of Cs2CO3 and t-BuOH provides a dramatic rate acceleration in the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols while maintaining the selectivity of the process.