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Optimal Design of Solvent Blend and Its Application in Coking Wastewater Treatment Process

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journal contribution
posted on 01.10.2014 by Mingsen Liao, Yuehong Zhao, Pengge Ning, Hongbin Cao, Hao Wen, Yi Zhang
One of the key steps of coking wastewater treatment is phenolic and tar removal via extraction. However, the high loss of the extractant, i.e., methyl isobutyl ketone (MIBK), leads to the high cost of the process. The adoption of a novel solvent or solvent blend is considered as an efficient way to address this problem. In this paper, seven solvents (benzene, toluene, m-xylene, ethylbenzene, 1, 3, 5-trimethylbenze, cyclohexane, and octanol), selected as candidate diluters for MIBK according to operating requirements, are studied with a nonlinear programming (NLP) model based on ideal counter-current extraction. The results, verified with experiments, suggest toluene is the most promising candidate. Further investigation of this solvent blend reveals that both Dblend (the distribution coefficient of phenol between solvent blend and water) and mMIBK (the MIBK concentration in raffinate) increase with xMIBK (the molar fraction of MIBK in blend). The trade-off between the extraction performance and MIBK loss recommends the blend with xMIBK = 0.05 as extractant for coking wastewater treatment. An industrial process consisting of extraction, back stripping, distillation, and mixer is presented. A corresponding NLP model is established for its operating optimization. To improve the accuracy, the representatives of typical phenolics and tar in wastewater (2,4 dimethyl phenol, m-xylene, and quinolone) are also considered in addition to phenol. The case study indicates that the blend exhibits economic advantage over pure MIBK with a makeup cost of 11.15 ¥/t, much less than the 185.15 ¥/t in the case of MIBK.