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One-Pot, Catalytic, Asymmetric Synthesis of Polypropionates

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journal contribution
posted on 10.04.2001 by Michael A. Calter, Xin Guo, Wensheng Liao
The opening of methylketene dimer, followed by aldol reactions of the resulting enolate, provides a convenient access to syn,syn-dipropionate aldol adducts of a variety of aldehydes. These aldol adducts are useful precursors in the synthesis of complex polypropionates.

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