am5b01532_si_001.pdf (1.28 MB)
0/0

Oligomer-Coated Carbon Nanotube Chemiresistive Sensors for Selective Detection of Nitroaromatic Explosives

Download (1.28 MB)
journal contribution
posted on 15.04.2015 by Yaqiong Zhang, Miao Xu, Benjamin R. Bunes, Na Wu, Dustin E. Gross, Jeffrey S. Moore, Ling Zang
High-performance chemiresistive sensors were made using a porous thin film of single-walled carbon nanotubes (CNTs) coated with a carbazolylethynylene (Tg-Car) oligomer for trace vapor detection of nitroaromatic explosives. The sensors detect low concentrations of 4-nitrotoluene (NT), 2,4,6-trinitrotoluene (TNT), and 2,4-dinitrotoluene (DNT) vapors at ppb to ppt levels. The sensors also show high selectivity to NT from other common organic reagents at significantly higher vapor concentrations. Furthermore, by using Tg-Car/CNT sensors and uncoated CNT sensors in parallel, differential sensing of NT, TNT, and DNT vapors was achieved. This work provides a methodology to create selective CNT-based sensors and sensor arrays.

History

Exports