Olefin Ring Closing Metathesis and Hydrosilylation Reaction in Aqueous Medium by Grubbs Second Generation Ruthenium Catalyst
journal contributionposted on 19.09.2008 by Vivek Polshettiwar, Rajender S. Varma
Any type of content formally published in an academic journal, usually following a peer-review process.
The Grubbs second generation ruthenium catalyst was shown to catalyze various olefin ring closing metathesis and hydrosilylation reactions in aqueous medium. Reactions proceeded in pure water without any additives or cosolvents, in a short period of time. We found that inhomogeneity of the reaction mixture does not prevent high conversion (70−95%) of the products in both reactions.