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Luminescence Color Tuning by Regulating Electrostatic Interaction in Light-Emitting Devices and Two-Photon Excited Information Decryption

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posted on 14.02.2017 by Yun Ma, Shujuan Liu, Huiran Yang, Yi Zeng, Pengfei She, Nianyong Zhu, Cheuk-Lam Ho, Qiang Zhao, Wei Huang, Wai-Yeung Wong
It is well-known that the variation of noncovalent interactions of luminophores, such as π–π interaction, metal-to-metal interaction, and hydrogen-bonding interaction, can regulate their emission colors. Electrostatic interaction is also an important noncovalent interaction. However, very few examples of luminescence color tuning induced by electrostatic interaction were reported. Herein, a series of Zn­(II)-bis­(terpyridine) complexes (Zn-AcO, Zn-BF4, Zn-ClO4, and Zn-PF6) containing different anionic counterions were reported, which exhibit counterion-dependent emission colors from green-yellow to orange-red (549 to 622 nm) in CH2Cl2 solution. More importantly, it was found that the excited states of these Zn­(II) complexes can be regulated by changing the electrostatic interaction between Zn2+ and counterions. On the basis of this controllable excited state, white light emission has been achieved by a single molecule, and a white light-emitting device has been fabricated. Moreover, a novel type of data decryption system with Zn-PF6 as the optical recording medium has been developed by the two-photon excitation technique. Our results suggest that rationally controlled excited states of these Zn­(II) complexes by regulating electrostatic interaction have promising applications in various optoelectronic fields, such as light-emitting devices, information recording, security protection, and so on.

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