ja073084l_si_001.pdf (16.02 MB)

Iron-Catalyzed Selective Biaryl Coupling:  Remarkable Suppression of Homocoupling by the Fluoride Anion

Download (16.02 MB)
journal contribution
posted on 15.08.2007 by Takuji Hatakeyama, Masaharu Nakamura
In the presence of iron(III) fluoride and 1,3-bis(2,6-di-i-propylphenyl)imidazolinium chloride, aryl magnesium bromides react with aryl chlorides to give the corresponding cross-coupling products, unsymmetrical biaryls, in good to excellent yields.

History

Exports