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Ir(III)-Catalyzed Carbenoid Functionalization of Benzamides: Synthesis of N‑Methoxy­isoquinoline­diones and N‑Methoxy­isoquinolinones

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journal contribution
posted on 26.05.2016, 13:51 by Ravindra S. Phatake, Pitambar Patel, Chepuri V. Ramana
A mild and efficient Ir­(III)-catalyzed C–H carbenoid functionalization strategy has been developed to access N-methoxyiso­quinolinediones and N-methoxy­isoquinolinones. The reaction proceeds efficiently in high yield at room temperature over a broad range of substrates without requirement of any additional oxidants or a base.

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