Intramolecular C−H Amination Reactions: Exploitation of the Rh2(II)-Catalyzed Decomposition of Azidoacrylates
journal contributionposted on 20.06.2007 by Benjamin J. Stokes, Huijun Dong, Brooke E. Leslie, Ashley L. Pumphrey, Tom G. Driver
Any type of content formally published in an academic journal, usually following a peer-review process.
Rhodium(II) perfluorobutyrate-mediated decomposition of vinyl azides provides a new, mild entry into Rh2(II) nitrenoid chemistry. This methodology allows rapid access to a variety of complex, functionalized N-heterocycles in two steps from commercially available starting materials.