Hexanuclear Platinum(II) Thiolate Macrocyclic Host: Charge-Transfer-Driven Inclusion of a AgI Ion Guest
journal contributionposted on 08.09.2016 by Yukatsu Shichibu, Keisuke Yoshida, Katsuaki Konishi
Any type of content formally published in an academic journal, usually following a peer-review process.
The inclusion of a AgI ion by a hexanuclear platinum(II) thiolate macrocycle in solution was demonstrated, and the inclusion structure was determined by X-ray crystallography. Unique host–guest intermetallic interactions driven by charge transfer were elucidated by optical absorption spectroscopy and theoretical calculations.