ic6b01579_si_001.pdf (462.46 kB)

Hexanuclear Platinum(II) Thiolate Macrocyclic Host: Charge-Transfer-Driven Inclusion of a AgI Ion Guest

Download (462.46 kB)
journal contribution
posted on 08.09.2016 by Yukatsu Shichibu, Keisuke Yoshida, Katsuaki Konishi
The inclusion of a AgI ion by a hexanuclear platinum­(II) thiolate macrocycle in solution was demonstrated, and the inclusion structure was determined by X-ray crystallography. Unique host–guest intermetallic interactions driven by charge transfer were elucidated by optical absorption spectroscopy and theoretical calculations.

History

Exports