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Glycoluril Dimers Bearing Hydrogen Atoms on Their Convex Face and Their Self-Assembly in the Solid State

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journal contribution
posted on 20.06.2008 by Marek Stancl, Marek Necas, Jan Taraba, Vladimir Sindelar
A selective method for the synthesis of 1,6-substituted glycolurils has been developed. The glycolurils have been used for the synthesis of methylene-bridged glycoluril dimers bearing hydrogen atoms on their convex face. Depending on the side walls of the dimers, different modes of self-assembly in the solid state have been described using X-ray crystallography.